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化学化工学院

黄国利                                      

有机化学专业,教授,硕士生导师

联系方式:hgli2005@126.comhuangguoli@ynnu.edu.cn

主要研究方向

可见光催化过渡金属催化;绿色合成

主要招生专业

有机化学

教育与工作经历

2023年12至今,云南师范大学化学化工学院,药物化学系,教授

2023年9月2024年8月,英国曼彻斯特大学化学系,访问学者

20179202311月,云南师范大学化学化工学院,药物化学系,副教授

2011年1020178月,云南师范大学化学化工学院,药物化学系,讲师

2008年9月~2011年9月,南京大学化学化工学院,有机化学,理学博士

2005年9月~2008年7月,西北师范大学化学化工学院,有机化学,理学硕士

获奖成果和荣誉称号

1. 云南省中青年学术和技术带头人后备人才,2023年

2. 云南师范大学红云园丁奖三等奖,2016年

3. 云南师范大学优秀硕士学位论文,2023年(指导老师:黄国利)

4. 云南师范大学优秀硕士学位论文,2022年(指导老师:黄国利)

主持科研项目

1. 国家自然科学基金项目,可见光调控苯基桥联1,6-烯炔的串联环化反应构建双官能团化茚类,执行时间:2024/01-2027/12

2. 云南省科技人才与平台计划,中青年学术和技术带头人后备人才项目,执行时间:2024/01-2028/12

3. 国家自然科学基金项目,自由基介导醛/磷氧化物对腈和炔的酰化/磷酰化环化反应研究,执行时间:2019/01-2022/12

4. 云南省基础研究计划项目,自由基型醛与腈的酰化-环化反应及其药物合成应用,执行时间:2019/07-2022/06

5. 云南省基础研究计划项目,稠杂环C-H键功能化及其生物活性研究,执行时间:2013/10-2016/09

6. 云南省教育厅科学研究基金项目,咪唑[2,1-b]噻唑C-H键功能化研究,执行时间:2012/07-2014/12

代表性著作、论文、专利等

1. Xiao Hu, Bo-Xin Chen, Xiang-Lin Bo, Qing-Fang Zhang, Lin-Ping Hu, Ming-Yu Teng, Guo-Li Huang*, Bo Liu*. Visible Light-induced Cyanomethyl Radical Triggered Cascade Cyclization of Phenyl-Linked 1,6-Enynes with a-Halogenated Acetonitriles. Adv. Synth. Catal., 2024 (DOI: 10.1002/adsc.202400878)

2. Xiao-Hong Huang, Xiao Hu, Ting-Feng Fu, Ya-Yu Wang, Ming-Yu Teng, Guo-Li Huang*, Bo Liu*. Visible Light-Promoted and Catalyst-Controlled aAminoalkylation and aDiaminoalkylation of Morita-Baylis-Hillman Acetates with NMethyl Arylamines: Divergent Synthesis of NContaining Alkyl Acrylates and γ,γ-Diaminobutyl Esters. J. Org. Chem., 2024, 89, 18412-18423

3. De-Run Zhang, Lin-Ping Hu, Feng-Lin Liu, Xiao-Hong Huang, Xia Li, Bo Liu, Ming-Yu Teng, Guo-Li Huang*. Catalyst-controlled and Visible Light-induced Acylmethylation and Bromoacylmethylation of Morita-Baylis-Hillman Acetates with α-Bromo Ketones: Access to Highly Functionalized 1,5-Dicarbonyl Compounds. Org. Chem. Front., 2023, 10, 4927-4934

4. Xiao-Hong Huang, Feng-Lin Liu, Ting-Feng Fu, Xiao Hu, Ya-Yu Wang, Bo Liu, Ming-Yu Teng, Guo-Li Huang*. Visible Light-induced Radical Cascade Acylmethylation/Cyclization of 2-(Allyloxy)arylaldehydes with α-Bromo Ketones: Access to Cyclic 1,5-Dicarbonyl-containing Chroman-4-one skeletons. Org. Biomol. Chem., 2023, 21, 6772-6777

5. Xiao-Hong Huang, Cai-Yun Yang, Feng-Lin Liu, Xia Li, Bo Liu, Jun-Feng Kou, Guo-Li Huang*, Ming-Yu Teng*. Palladium/Norbornene Cooperative Catalyzed Cascade Decarboxylative Cyclization of 4-Iodoisoquinolin-1(2H)-ones with o-Bromobenzoic Acids: Access to Diverse Fused Phenanthridinones and Hepta[1,2-c]isoquinolinones. J. Org. Chem., 2023, 88, 8329-8344

6. De-Run Zhang, Lin-Ping Hu, Feng-Lin Liu, Xiao-Hong Huang, Xia Li, Bo Liu, Guo-Li Huang*. Metal-free, Visible-light-promoted Decarboxylative Alkylation of Baylis-Hillman Acetates with N-(acyloxy)phthalimides. Green Chem., 2022, 24, 6840-6844

7. Lin-Ping Hu, De-Run Zhang, Xiao-Hong Huang, Feng-Lin Liu, Xia Li, Ming-Yu Teng, Guo-Li Huang*. Metal-Free Arylsulfonyl Radical Triggered Cascade Cyclization of Phenyl-Linked 1,6-Enynes: Synthesis of 2,3-Dihydro-1H-indenes and 10a,11-Dihydro-10H-benzo[b]fluorines. Chin. J. Chem., 2022, 40, 2756-2762

8. De-Run Zhang, Lin-Ping Hu, Cai-Yun Yang, Xia Li, Ming-Yu Teng, Bo Liu, Guo-Li Huang*. Tetramethylammonium Iodide (TMAI)-promoted Sulfenylation/Annulation of Enaminones with Thiosulfonates. Asian J. Org. Chem., 2022, 11, e202100694

9. Cai-Yun Yang, Lin-Ping Hu, De-Run Zhang, Xia Li, Ming-Yu Teng, Bo Liu, Guo-Li Huang*. p-Toluenesulfonic Acid-catalyzed Regioselective C4-H Iodination of Isoquinolin-1(2H)-ones. New J. Chem., 2022, 46, 10934-10939

10. Cai-Yun Yang, Xia Li, Bo Liu, Guo-Li Huang*. I2-promoted Direct C-H Sulfenylation of Isoquinolin-1(2H)-ones with Sulfonyl Chlorides. Eur. J. Org. Chem., 2021, 117-124

11. Cai-Yun Yang, De-Run Zhang, Lin-Ping Hu, Xia Li, Shi-Chen Yang, Bo Liu*, Guo-Li Huang*.

Visible-light-induced sulfonylation of Baylis–Hillman acetates under metal- and oxidant-free conditions. New J. Chem., 2021, 45, 22243-22248

12. Fei Li, Xiao-Juan Gu, Chang-E Zeng, Xia Li, Bo Liu, Guo-Li Huang*. Copper(I)/bpy-catalyzed C-2-H Benzylation of Quinazolin-4(3H)-ones with N-tosylhydrazones Eur. J. Org. Chem., 2020, 2923-2928

13. Guoli Huang*, Mingyu Teng, Bo Liu, Meizhu Rong, Ying Liu, Yegao Chen*. Palladium-catalyzed Site-selective C-H Alkenylation of Imidazo[2,1-b]thiazoles. J. Organomet. Chem., 2016, 818, 163-167

14. Yuchang Ma, Min Na, Yanfang Gu, Guo-Li Huang*, Xia Li, Yegao Chen*. Direct Arylation of Imidazo[2,1-b]thiazoles and Thiazoles with Aryl Iodides via CuCl2/PPh3-catalyzed C-H Bond Functionalization. Appl. Organomet. Chem., 2015, 29, 165-169

15. Yalin Diao, Rong Hao, Junfeng Kou, Mingyu Ten, Guo-Li Huang*, Yegao Chen*. Synthesis, Structural Characterization and Catalytic Activity of Benzimidazole-functionalized Pd(II) N-heterocyclic Carbene Complexes. Appl. Organomet. Chem., 2013, 27, 546-551

16. Guoli Huang, Hongsheng Sun, Xiaojie Qiu, Yingzhong Shen, Juli Jiang*, Leyong Wang*. Synthesis, Structural Characterization of Benzimidazole-functionalized Ni(II) and Hg(II) N-heterocyclic Carbene Complexes and Their Applications as Efficient Catalysts for Friedel-Crafts Alkylations. J. Organomet. Chem., 2011, 696, 2949-2957

17. Guoli Huang, Hongsheng Sun, Xiaojie Qiu, Can Jin; Chen Lin, Yingzhong Shen, Juli Jiang*, Leyong Wang*. Ligand-free Copper-catalyzed Regioselective C-2 Arylation of Imidazo[2,1-b]thiazoles. Org. Lett., 2011, 13, 5224-5227

18. 黄国利,李霞,杨彩云,专利名称:一种制备4-碘异喹啉-1(2H)-酮类化合物的方法,发明专利,专利授权号:ZL 202210348648.2,专利授权日期:2023/09

19. 黄国利,李霞,杨彩云,专利名称:一种制备苯并呋喃-2-甲酰胺类化合物的方法,发明专利,专利授权号:ZL 201911092582.X,专利授权日期:2023/05

主持教学改革项目

1.云南师范大学课程思政建设项目,药物合成,2022

主讲课程

本科生课程《有机化学、《有机化学实验》、《药物合成》、《药物化学实验》、《天然药物化学实验》

研究生课程《现代化工前沿进展